While in UEFI mode, the Windows version must match the PC architecture. A 64-bit UEFI PC can only boot 64-bit versions of Windows. A 32-bit PC can only boot 32-bit versions of Windows. In some cases, while in legacy BIOS mode, you may be able to run 32-bit Windows on a 64-bit PC, assuming the manufacturer supports 32-bit legacy BIOS mode on the PC.